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ARS Home » Midwest Area » Peoria, Illinois » National Center for Agricultural Utilization Research » Bio-oils Research » Research » Publications at this Location » Publication #304385
Title: Thiol-ene and H-phosphonate-ene reactions for lipid modifications

Author
item Bantchev, Grigor
item Cermak, Steven - Steve
item Biresaw, Girma
item Appell, Michael
item Kenar, James - Jim
item Murray, Rex

Submitted to: Book Chapter
Publication Type: Book / Chapter
Publication Acceptance Date: 6/7/2014
Publication Date: 11/3/2014
Citation: Bantchev, G.B., Cermak, S.C., Biresaw, G., Appell, M., Kenar, J.A., Murray, R.E. 2015. Thiol-ene and H-phosphonate-ene reactions for lipid modifications. In: Liu, Z., Kraus, G., editors. Green Materials from Plant Oils. 1st edition. Cambridge, UK: RSC Publishing. p. 59-92.

Interpretive Summary:

Technical Abstract: The addition of H-E (E= -SR, -P(O)(OR)2 or -P(O)R2) to the carbon-carbon double bonds in lipids is a way to create new materials: lubricants, additives, polymers. In the current chapter, the radical addition of thiols (E= SR) and H-phosphonates (E= P(O)(OR)2) will be reviewed in detail. The kinetics of the reactions is discussed. The use of the reactions to introduce different functional groups and the way to synthesize various functional materials is presented.