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ARS Home » Pacific West Area » Riverside, California » U.S. Salinity Laboratory » Contaminant Fate and Transport Research » Research » Publications at this Location » Publication #221408


item Franklin, Mariza
item Fernandes, Horst
item Van Genuchten, Martinus
item Vargas, Jr., Euripedes
item Azevedo, Jose

Submitted to: Meeting Proceedings
Publication Type: Proceedings
Publication Acceptance Date: 8/1/2007
Publication Date: 9/6/2007
Citation: Franklin, M., Fernandes, H., Van Genuchten, M.T., Vargas, Jr., E., Azevedo, J.P. 2007. Application of water flow and geochemical models to support the remediation of acid rock drainage from the uranium mining site of Pocos De Caldas, Brazil. Meeting Proceedings. 11th International Conference on Environmental Remediation and Radioactive Waste Management 2007 Sep 2-6, 2007 Paper No. 07-7346

Interpretive Summary: n 1982 Brazil started its first uranium production center in Pocos de Caldas in the state of Minas Gerais. After 13 years of intermittent operation, the mining activities were suspended in 1995. Uranium was extracted by open pit mining. While several hydrogeologic and geochemical studies of the site had been carried out, a long-term plan for remediation of the site was never implemented. This includes studies of acid mine drainage from the waste rock deposited near the site. Accurate estimates of the release rates of metals and radiocuclides and their transport into the subsurface environment are critical to assessing their impact on the environment and developing effective remediaiton schemes. In this study we used the HYDRUS-2D and STEADQL-v4 numerical codes to simulate water flow and geochemical processes, respectively, in one of the waste rock piles at the site. This paper describes the approach used to obtain detailed conceptual representations of the flow regime at the site, and the many geochemical reactions thought to be present. The estimated seepage flow rate from the site was found to be in relatively good agreement with measured data. Preferential flow of water through the fractured rock waste site was shown to have a major effect on the predictions. The separate fluid flow and geochemical calculations provided considerable insight in the processes controlling acid rock drainage, and should serve as an initial step to application of more realistic coupled models.

Technical Abstract: This paper discusses the use of two numerical models (HYDRUS-2D and STEADQL-v4) for simulating water flow and relevant geochemical processes in one of the waste rock piles of the first uranium mine in Brazil, in order to facilitate the selection of appropriate remediation strategies. The long time scale required for the oxidation of sulfidic wastes (at least 600 years) implies the need to implement permanent remediation actions. The best remediation scheme should depend on the water flow regime inside the waste pile and on the geochemical processes that occur as a result of the interactions between water and the waste (especially oxidative dissolution of pyrite). Accurate modeling of the waste site, which contains a wide range of grain and rock sizes at different degrees of water saturation and is subject to reactive multicomponent transport, entails considerable physical, mathematical and numerical challenges. This paper describes the approach used to obtain a detailed representation of the system involving both unsaturated/saturated flow (most of the physical properties of the waste were estimated from measured data) and the geochemical network reactions (including equilibrium and kinetics reactions).