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United States Department of Agriculture

Agricultural Research Service

Research Project: THERMOCHEMICAL PROCESSING OF AGRICULTURAL WASTES TO VALUE-ADDED PRODUCTS AND BIOENERGY

Location: Commodity Utilization Research

2011 Annual Report


1a. Objectives (from AD-416)
The research objectives are to develop slow pyrolysis (or torrefaction) and activation processes to convert agricultural feedstock (crop residues, manures, processing wastes, and biorefinery by-products) into: (1) chars that can be used as industrial adsorbents; (2) chars that can be used as soil amendments which improve soil quality, water quality, and sequester carbon; (3) chars that can be used as energy sources (in combustion or gasification); and (4) bio-gas and bio-oil co-products that provide some of the heat and power requirements of the pyrolysis/torrefaction/activation operations and possibly excess heat/power for sale.


1b. Approach (from AD-416)
The approach will be to take agricultural feedstocks (crop residues, animal manure, and biorefinery waste) and heat them under different gas atmospheres to a set temperature. In order to create chars for target applications, the temperature, heating time, and gas atmosphere will be varied, as well as performing pretreatment (before heating) or post treatment of the chars to obtain desired properties. The products will be tested for target applications in our laboratories and also with collaborators with expertise in ammonia adsorption, soil amendments, bio-oil production, and large-scale pyrolysis.


3. Progress Report
Considerable progress has been made on the process for developing of advanced materials to remove (or stabilize) pollutants in soil, water, and air or to serve as an additive to soil. Future work will also investigate the possibility of using these materials as fuels. Biochars (plant or animal waste heated without air) were produced by heating cotton seed hulls, almond shells, biorefinery waste lignin (woody byproduct), and chicken manure in a hot oven to several different temperatures. They were kept in the oven for 1 to 4 hours. After cooling, these biochars were washed in water or left un-washed and inspected both physically and chemically. We found that the materials kept their density unless the oven was very hot (800° Centigrade). In the hotter oven small channels (pores) developed in the chars which increased the active surface area. However, this was not true for all the starting materials. For example, almond shell char did not develop pores even at 800°. If steam was added to the oven above the chars, the active surface area increased in all cases. Previous studies had shown that mercury could be removed from air using biochars made from chicken and turkey manure. In new studies, we replaced the air with a gas similar to the one seen in exhausts from coal-fired power plants. The un-washed biochars made from chicken manure worked very well and removed almost all the mercury form the gas. Biochars made from turkey manure also worked well if it was washed. Washing adds additional cost to the process. A manuscript was published with the results. Biochars made at 350° from cotton seed hulls was effective in removing copper, nickel, cadmium, and lead from a water and soil system. Later studies investigated the importance of chemical composition and function of the surface of the biochars; it was noted that the chars made at low temperature contained more oxygen groups, which are known to attract metal contaminants. Biochar made from chicken manure was also effective in removing metals (except nickel) from the same type of system. Experiments with different types of soils and natural organic matter (found in many soils) showed that the natural organic matter prevented some of the metals to adsorb to the chars. Multiple manuscripts were published with the results. Work with collaborations showed that biochars left from a process to make bio-oils (by very fast heating of powdered biomass) could later be slowly heated in the presence of steam to make biochars that were better (on average) at removing metals, such as copper, nickel, cadmium, and zinc from water, than the starting biochars. Using electron microscopy, we were able to show that pores were made by the steam and this resulted in more surface area per weight of biochar.


4. Accomplishments


Review Publications
Uchimiya, M., Wartelle, L.H., Lima, I.M., Klasson, K.T. 2010. Sorption of deisopropylatrazine on broiler litter biochars. Journal of Agricultural and Food Chemistry. 58(23):12350-12356.

Uchimiya, M., Klasson, K.T., Wartelle, L.H., Lima, I.M. 2011. Influence of soil properties on heavy metal sequestration by biochar amendment: 1. copper sorption isotherms and the release of cations. Chemosphere. 82(10):1431-1437.

Klasson, K.T., Lima, I.M., Boihem, L.L., Wartelle, L.H. 2010. Feasibility of mercury removal from simulated flue gas by activated chars made from poultry manures. Journal of Environmental Management. 91(12):2466-2470.

Uchimiya,M., Gorb, L., Isayev, O., Qasim, M.M., Leszczynski, J. 2010. One-electron standard reduction potentials of nitroaromatic and cyclic nitramine explosives. Environmental Pollution. 158(10):3048-3053.

Uchimiya, M., Klasson, K.T., Wartelle, L.H., Lima, I.M. 2011. Influence of soil properties on heavy metal sequestration by biochar amendment: 2. copper desorption isotherms. Chemosphere. 82(10):1438-1447.

Uchimiya, M., Wartelle, L.H., Klasson, K.T., Fortier, C.A., Lima, I.M. 2011. Influence of pyrolysis temperature on biochar property and function as heavy metal sorbent in soil. Journal of Agricultural and Food Chemistry. 59:2501-2510.

Klasson, K.T., Taylor, P.A. 2006. Remediation of groundwater contaminated with radioactive compounds. On line web access only at www.eolss.net.

Lima, I.M., Boateng, A.A., Klasson, K.T. 2010. Physicochemical and adsorptive properties of fast-pyrolysis bio-chars and their steam activated counterparts. Journal of Chemical Technology & Biotechnology. 85(11):1515-1521.

Uchimiya, M., Lima, I.M., Klasson, K.T., Wartelle, L.H. 2010. Contaminant Immobilization and Nutrient Release by Biochar Soil Amendment: Roles of Natural Organic Matter. Chemosphere. 80 (8):935-940.

Uchimiya, M. 2010. Reductive transformation of 2,4-dinitrotoluene: roles of iron and natural organic matter. Aquatic Geochemistry. 16(4):547-562.

Uchimiya, M., Chang, S., Klasson, K.T. 2011. Screening biochars for heavy metal retention in soil: role of oxygen functional groups. Journal of Hazardous Materials. 190:432-441.

Klasson, K.T., Uchimiya, M., Lima, I.M., Boihem, Jr., L.L. 2011. Feasibility of removing furfurals from sugar solutions using activated biochars made from agricultural residues. BioResources. 6(3):3242-3251.

Last Modified: 10/20/2017
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