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United States Department of Agriculture

Agricultural Research Service

Title: Screening for Volatile Organic Fatty Acids in Agricultural Air Using Solid-Phase Microextraction and Gas Chromatography-Mass Spectrometry

item Spinhirne, Jarett - TX AG. EXPERIMENT STATION
item Koziel, Jacek - TX AG. EXPERIMENT STATION
item Parker, David - WEST TEXAS A&M UNIV.
item Williams, Darren - BWXT PANTEX
item Sweeten, John - TX AG. EXPERIMENT STATION

Submitted to: Proceedings of the American Society of Agricultural and Biological Engineers International (ASABE)
Publication Type: Proceedings
Publication Acceptance Date: June 21, 2002
Publication Date: July 31, 2002
Repository URL:
Citation: Spinhirne, J.P., Koziel, J.A., Parker, D.B., Williams, D.L., Cole, N.A., Sweeten, J.M. 2002. Screening for volatile organic fatty acids in agricultural air using solid-phase microextraction and gas chromatography-mass spectrometry. In: Proceedings of the American Society of Agricultural and Biological Engineers (ASABE) Annual International Meeting, July 28-31, 2002, Chicago, Illinois. Paper No. 024163.

Technical Abstract: Volatile fatty acids (VFAs) are a major component of odorous gases associated with agricultural sources. Because of typically low VFA air concentrations, conventional air sampling methods including sorbent tubes and vacuum canisters are often not sensitive enough to detect them. Solid phase microextraction (SPME) was used in this research because it is very sensitive, reusable, fast, and combines sampling and sample preparation, allowing for rapid detection of low concentrations of organics in air. This research focused on 7 VFAs: acetic, propionic, isobutyric, butyric, isovaleric, valeric, and hexanoic acids. Field experiments were conducted to test this method for air sampling of beef cattle feedyard, house manure compost, and a swine operation in Texas. Rapid SPME samples were collected by exposing DVB/Carboxen/PDMS 50/30 µm SPME fibers to air for 1 to 5 min. Sample preservation was accomplished by plugging of fiber assemblies with simple PTFE caps for transport to the laboratory for analysis on gas chromatograph-mass spectrometer (GC-MS). SPME DVB/Carboxen/PDMS 50/30 µm coating was very effective in detecting target VFAs and other gaseous components of agricultural odors. This coating was also very efficient in retaining major fraction of target VFAs.

Last Modified: 4/22/2015
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