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ARS Home » Southeast Area » Stoneville, Mississippi » Warmwater Aquaculture Research Unit » Research » Publications at this Location » Publication #341050
Research Project: Umbrella Project for Food Safety

Location: Warmwater Aquaculture Research Unit

Title: Transparent bionanocomposite films based on chitosan and TEMPO-oxidized cellulose nanofibers with enhanced mechanical and barrier properties

Author
item SONI, BHAWNA - Mississippi State University
item HASSAN, E - Mississippi State University
item SCHILLING, M - Mississippi State University
item MAHMOUD, B - Mississippi State University

Submitted to: Carbohydrate Polymers
Publication Type: Peer Reviewed Journal
Publication Acceptance Date: 6/3/2016
Publication Date: 6/6/2016
Citation: Soni, B., Hassan, E., Schilling, M.W., Mahmoud, B. 2016. Transparent bionanocomposite films based on chitosan and TEMPO-oxidized cellulose nanofibers with enhanced mechanical and barrier properties. Carbohydrate Polymers. doi:e10.1016.

Interpretive Summary: The development of biobased active films for use in food packaging is increasing due to low cost, environmental appeal, renewability and availability. The objective of this research was to develop an effective and complete green approach for the production of nanocellulose/chitosan bionanocomposite films for food packaging applications.

Technical Abstract: In this study, TEMPO-oxidized cellulose nanofibers (2,2,6,6-tetramethylpiperidine-1-oxyl radical) was incorporated into a chitosan matrix. An aqueous suspension of chitosan (100-75 wt %), sorbitol (25 wt %) and TEMPO-oxidized cellulose nanofibers (TEMPO-CNFs, 0-25 wt %) were cast in an oven at 40 °C for 2-4 days. Films were preconditioned at 25°C and 50% RH for characterization. The surface morphology of the films was revealed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The thermal properties and crystal structure of the films were evaluated by thermogravimetric analysis (TGA-DTG) and X-ray diffraction (XRD). Incorporation of TEMPO-CNFs enhanced the mechanical strength of the films due to the high aspect ratio (3-20 nm width, and 10-100 nm length) of TEMPO-CNFs and strong interactions with the chitosan matrix. Oxygen and water vapor transmission rates for films that are prepared with chitosan and TEMPO-CNFs (15-25 wt %) were significantly reduced. Furthermore, these bionanocomposite films had good thermal stability. Use of TEMPO-CNFs in this method makes it possible to produce bionanocomposite films that are flexible, transparent, and thus have potential in food packaging applications.